Search results for "Rabi splitting"

showing 3 items of 3 documents

Vacuum Rabi splitting for surface plasmon polaritons and Rhodamine 6G molecules

2011

We report on strong coupling between surface-plasmon polaritons and Rhodamine 6G molecules at room temperature. As a reference to compare with, we first determine the dispersion curve of (uncoupled) surface plasmon polaritons on a 50 nm thick film of silver. Consequently, we determine the dispersion curve of surface plasmon polaritons strongly coupled to Rhodamine 6G molecules, which exhibits vacuum Rabi splitting. Depending on the Rhodamine 6G concentration, we find splitting energies between 0.05 eV and 0.13 eV.

Materials scienceta214Condensed matter physicsta114Surface plasmonta221educationtechnology industry and agriculturevacuum Rabi splittingdispersion curveMolecular physicsSurface plasmon polaritonRhodamine 6Gchemistry.chemical_compoundchemistrysurface plasmon polaritonDispersion (optics)strong couplingStrong couplingPolaritonMoleculeta218Localized surface plasmon
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Reversible Strong Coupling in Silver Nanoparticle Arrays Using Photochromic Molecules

2012

International audience; In this Letter, we demonstrate a reversible strong coupling regime between a dipolar surface plasmon resonance and a molecular excited state. This reversible state is experimentally observed on silver nanoparticle arrays embedded in a polymer film containing photochromic molecules. Extinction measurements reveal a clear Rabi splitting of 294 meV, corresponding to ∼13% of the molecular transition energy. We derived an analytical model to confirm our observations, and we emphasize the importance of spectrally matching the polymer absorption with the plasmonic resonance to observe coupled states. Finally, the reversibility of this coupling is illustrated by cycling the …

exciton−plasmon couplingPlasmonBioengineering02 engineering and technology010402 general chemistryPhotochemistry01 natural sciencesSilver nanoparticlePhotochromismchemistry.chemical_compoundactive plasmonicsGeneral Materials Science[SPI.NANO]Engineering Sciences [physics]/Micro and nanotechnologies/MicroelectronicsSurface plasmon resonancePlasmonRabi splittingSpiropyranChemistryMechanical EngineeringResonanceGeneral Chemistry021001 nanoscience & nanotechnologyCondensed Matter Physicsspiropyran0104 chemical sciencesChemical physicsExcited state[SPI.OPTI]Engineering Sciences [physics]/Optics / Photonic0210 nano-technologyLocalized surface plasmonNano Letters
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Strong coupling between surface plasmon polaritons and Sulforhodamine 101 dye

2011

We demonstrate a strong coupling between surface plasmon polaritons and Sulforhodamine 101 dye molecules. Dispersion curves for surface plasmon polaritons on samples with a thin layer of silver covered with Sulforhodamine 101 molecules embedded in SU-8 polymer are obtained experimentally by reflectometry measurements and compared to the dispersion of samples without molecules. Clear Rabi splittings, with energies up to 360 and 190 meV, are observed at the positions of the dye absorption maxima. The split energies are dependent on the number of Sulforhodamine 101 molecules involved in the coupling process. Transfer matrix and coupled oscillator methods are used to model the studied multilaye…

Materials scienceNanochemistryPhysics::Opticsdispersion curve02 engineering and technology01 natural sciencesMolecular physicschemistry.chemical_compoundOpticsMaterials Science(all)Dispersion relationstrong coupling0103 physical sciencesDispersion (optics)General Materials Science010306 general physicsReflectometryRabi splittingNano Expressbusiness.industrySulforhodamine 101Surface plasmon021001 nanoscience & nanotechnologySulforhodamine 101Condensed Matter PhysicsSurface plasmon polariton3. Good healthchemistrysurface plasmon polariton0210 nano-technologybusinessLocalized surface plasmonNanoscale Research Letters
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